I think I might put the light/device definitions in an array to make it easier to process. You might also want to think whether you might need a scene to cover more than a single zone - I would certainly want that.
But it all hinges on how you want to actually use the data. As mentioned elsewhere in the thread, it may be a lot more useful to have the array as an array-like object, particularly if you expect it to mainly be used by scene.
{
"Getting Dressed": [
{
"lightingzone": "3F_Bedroom",
"devices": [
{
"name": "ceiling",
"value": "255",
},
{
"name": "floor",
"value": "255,255,255,255",
},
...
],
...
},
...
],
...
}
So you might want to map some of that out before committing to a schema.
To be worth putting into a node, you'd need to be sure that it would be easily usable by other people who are likely to have very different sets of data.