That isn't what I asked. Are you running an ssh shell into the pi or are you running it on a keyboard/display plugged into the pi?
I think it unlikely that nothing happens, it is just that what you hoped for does not happen. In your previous thread I suggested connecting debug nodes set to show Complete Message to all outputs of the exec node and looking to see what they show. Did you do that?
If run as a service node-red in the background won’t have a display attached so it won’t be able to open the browser etc. You may be able to add a DISPLAY setting to the command.
No, it should be something like DISPLAY=:1 usr/bin/python /home/pi/naver.py
or perhaps :0, it is not easy to predict which virtual display will work.
That was why I asked whether it worked from an ssh shell, which you apparently ignored, as that would exhibit the same issue, if this is indeed the problem.