But you are running node-red on a synology, which means docker and docker means container, which are isolated from the host system - it will not be able to reach this path.
Something in your flows is trying to access dbus. I suggest you disable all the flow tabs and make sure it stops, then enable tabs until it happens again, hopefully that will give you a clue about it.
Thanks for the information. If so, that's great. I thought the problem was directly with node-red, if it's a problem with some flow, I'll find it soon and fix it :).